71. Which of the following is correct order of stability? (1) [NiCl4] 2 < [PdCl4] 2 < [PtCl4] 2 (2) [Co(H2O)6] 3 < [Co(NH3)6] 3 < [Co(CN)6] 3 (3) [Co(H2O)6] 3 < [Rh(H2O)6] 3 < [Ir(H2O)6] 3 (4) All of these
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Answer:
1. is correct order of stability
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stability of complex compound is depends on the following factors
- higher charge of central atom
- greater base strength of the compound
- and ring formation
the correct answer is option D .
- we can arrange the stability order with the help of spectrochemical series
- spectrochemical series
- Br⁻ < SCn⁻ < Cl⁻< S⁻< No3⁻ < F⁻< OH< C2O4⁻< H2O < NCS< edta< NH3< en< NO2< CN< CO
- as the + I effect increase compound become more stable
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