75% of the fiest order reaction is completed in 32 minute ;when was the 50 %reaction completed
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Let initial amount = A
after 32 minutes = 75% of A completed = 0.75A
we know , formula for 1st order reaction ,
K = 2.303/t log[ initial ]/[final]
= 2.303/32 log{ A/(A - 0.75A)}
={2.303/32}× log4 --------(1)
for half life , formula is
T½ = 2.303/K log2
put K ={2.303/32} × log4
T½ = 2.303/[{2.303/32} × log4 ] × log2
= 32 log2/log4
= 32log2/2log2
= 16 min
hence, half life of given reaction is 16 minutes .
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