(83.)
In the reaction given below identify ‘Z'
HCONHR +Pocl3→Z+H2O
(1) RCN
(2) RN=C = 0
(3) R-NC
(4) None of these
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Answered by
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In the reaction given below ‘Z' is :
Reaction :
HCONHR + POCl3 → Z + H2O
• This reaction is the reaction which dehydrate amides into nitrile.
• The amide reacts with POCl3 to form an intermediate that removes chloride ion.
• Followed by deprotonation at intermediate.
• At last, elimination of reactive intermediate gives
• HCONHR + POCl3 → R-NC + PClO2 + H2O
• Hence Z is R-NC
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