9.2 g of oil Saponification with 56 ml of 0.5 N alc KOH Solutionand on subseqt titration with 0.5 N HCI gave 15.2 ml as end point. A blank titration was conducted without taking the oil and repeating the same procedure gave 56 ml end point. calculate the Saponification value of oil sample. (May 2017)
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Saponification Value = (A - B) x N x 56.1 W This method is used to determine the total acid content, both free and combined, of tall oil. (Acid number only measures the free acid). The combined acids are primarily esters formed by reaction with the neutral components present in the original tall oil.
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