91) Highest peak in mass spectrum is called as?
a) Isotopic peak
b) base peak
c) Molecular ion peak
d) ionic peak
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b) base peak
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Answer:
b) base peak.
Explanation:
The base peak in toluene is due to loss of a hydrogen atom to form the relatively stable benzyl cation. This is thought to undergo rearrangement to form the very stable tropylium cation, and this strong peak at m/e = 91 is a hallmark of compounds containing a benzyl unit.
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