A 4% solution (w/w) of sucrose ( M = 342g/mol) in water has a freezing point of 271. 15 k. Calculate the freezing point of 5% glucose ( M = 180g/mol ) in water.
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Hi...
Here's ur answer...
Answer :
4% solution (w/w) of sucrose means 4g of sucrose in 96g water
Wsolvent = 96g, wsolute= 4g, Msolute= 342 g mol-1
Using the formula, ∆Tf = kf x m
(273.15 – 271.15) = 16.39
Kf = 16.39 K
For 5% solution (w/w) of sucrose means 5g of sucrose in 95g water
Wsolvent = 95g, wsolute= 5g, Msolute= 180 g mol-1
Using the formula, ∆Tf = kf x m
∆Tf = 0.48K
= 0.48 K
Tf = Tf0 - ∆Tf = (273.15 – 0.48) K = 272.67 K
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