Chemistry, asked by carlwilkinson8913, 1 year ago

A 600 W mercury lamp emits monochromatic radiation of wavelength 331.3 nm. How many photons are emitted from the lamp per second?
h = 6.62 × 10⁻³⁴ Js velocity of light = 3 × 10⁸ ms⁻¹
(a) 1.0 × 10¹⁹
(b) 1.0 × 10²³
(c) 1.0 × 10²¹
(d) 2.0 × 10²³

Answers

Answered by giprock2002
12
E_{photon} = h \cdot f
Here f is the frequency, h is the planck's constant.

Or  E_{p} = \frac{h \cdot c}{\lambda}

Let n = number of photons/second

E_{in-1-second} = n \cdot E_p = n \cdot \frac{h \cdot c}{\lambda}

i.e P = n \cdot E_p = n \cdot \frac{h \cdot c}{\lambda}, where P is power of lamp (given).

Solving for n:

n = 1.0 × 10^{21} (approximately)

This assumes that it converts all the power into light energy (though in reality it only converts about 5-9%, hence the answer would be 1/20th of this, but it's not in the options)
Answered by harsh2155yadav
5

Answer:

Explanation:

Let's first write down our givens for this problem

Given

Power

=

600

W

or

600

J

s

λ

=

331.3

nm

or

(

3.313

10

7

m

)

Now let's try to establish a few things.

The mercury lamp is emitting a certain amount of

Energy

per

second

, defined as its

Power

. The source is coming from a monochromatic radiation with a wavelength of

3.313

10

7

m

. We are asked to find how many photons are being emitted from the lamp that is providing

600

J

of energy per second.

Step 1: Figure out the energy associated with the photon

We use the following formula

a

a

a

a

a

a

a

a

a

a

a

a

a

a

a

E

=

h

f

Where

E = Energy of the photon (J)

h = Planck's constant

(

6.62

10

34

J*s

)

f = frequency of the photon

(

1

s

)

But we aren't given the frequency; we are give the wavelength.

Well, we know that the speed of light is constant and given as

3.00

10

8

m

s

and can be calculated by using the following:

a

a

a

a

a

a

a

a

a

a

a

a

a

c

=

f

λ

Where

c

=

speed of light

(

3.00

10

8

m

s

)

f

=

frequency of radiation

(

1

s

)

λ

=

wavelength

(

m

)

Knowing this, we can isolate to solve for the frequency

a

a

a

a

a

a

a

a

a

a

a

a

a

c

=

f

λ

c

λ

=

f

We can replace

f

in the energy of the photon equation with

c

λ

and solve.

E

=

h

f

E

=

h

c

λ

E

=

(

6.62

10

34

J

s

)

(

3.00

10

8

m

s

)

3.313

10

7

m

5.99

10

19

J

Step 2: Use dimensional analysis to figure out photons emitted per s

Well, what does this tell us? This tells us that 1 photon has

5.99

10

19

J

a

a

a

a

a

a

a

a

a

a

a

a

a

a

1

photon

5.99

10

19

J

We were also told that the lamp produced

600

J

per second

a

a

a

a

a

a

a

a

a

a

a

a

a

a

a

a

a

600

J

s

We can use dimensional analysis to figure out the number of photons emitted per second.

a

a

a

a

a

600

J

s

1

photon

5.99

10

19

J

1.00

10

21

photons

s

Answer

:

1.00

10

21

photons

s

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