A+B➡️C+D If initially of A and B are both are taken in equal amount but at equilibrium concentration of D will be twice of that of A then what will be the equilibrium constant of reaction :-
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Explanation:
Let the volume of the solution or container be = V.
Initial number of moles of A or B = N.
One mole of A and one mole of B give rise to one mole of C and one mole of D. Let there be X moles of C and X moles of D at the equilibrium. So X moles of A and X moles of B are consumed. Remaining amount of A or B will be N-X moles.
A + B = C + D
N-X N-X X Xmoles
[C] = [D] = X/V .... [A] = [B] = (N-X)/V
Given [D] = 2 [A]
=> X = 2(N-X) => X = 2N/3
Equilibrium constant = [ C ] [ D ] / { [ A ] [ B ] }
Kc = X² / (N-X)² = 4
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