A binary solution contains 4 mol of A and 6 mol of B.Its vapour pressure is found to be 460mm Hg.To this solution,when 10 mol of B is added,its vapour pressure becomes 480mm Hg.The vapour pressures of pure A and pure B,respectively,are
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Answer:
pA= 96mmHg
pB= 384 mmHg
Explanation:
concept- initial mole fraction of A and B in liquid solution is 0.4 and0.6 respectively
(mole fraction = na/na+nb)
vapour pressure initial = pi
Addition of 10 mole of B is added then mole fraction of A and B become 0.2 and 0.8 respectively
vapour pressure final= pf
vapour pressure of A = pA
vapour pressure of B = pB
pA= Xa* pf
pA= 0.2*480= 96mmHg
pB= Xb* pf
pB= 0.8* 480
pB= 384 mmHg
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