A closed system of constant volume experiences
a temperature rise of 25°C when a certain
process occurs. The heat transferred in the
process is 30 kJ. The specific heat at constant
volume for the pure substance comprising the
system is 1.2 kJ/kg°C, and the system contains
the
2.5 kg. of this substance. Determine:
(i) The change in internal energy
(ii) The work done.
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Answer:
Explanation:
Temperature rise(T2-T1)=25°C
the heat transferred Q=30kJ
specific heat at constant volume cv=1.2kJ/kg°C
mass of the substance m=2.5kg
ΔU=m∫T2 = cvdT
∫ T1
=2.5∫T2 1.2dT= 3.0*(T2-T1)
T1
= 3.0*2.5 = 75kJ
thus change in internal energy is 75kJ
according to the first law of thermodynamics,
Q=ΔU + W
30=75+ W
W=75-30= -45 kJ
thus work done is -45kJ
Hope this helps
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