• A compound is 21.20%. Nitrogen, 6.06 percent of hydrogen,
24.30% sulpur and 48.45 percent oxygen. Write the
Empirical formula for the compound.
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Solution :-
- % N = 21.02
- %H = 6.06
- %S = 24.30
- %O = 24.30
Relative no of atoms
Divide the % composition of elements with their respective atomic masses
- Atomic mass of N = 14
- Atomic mass of H = 1
- Atomic mass of S = 32
- Atomic mass of O = 16
⇒ N = 21.20 / 14 = 1.5
⇒ H = 6.06 / 1 = 6.06
⇒ S = 24.3 / 32 = 0.75
⇒ O = 48.45 /16 = 3.02
Simple Ratio
Now divide all the values obtained above with the least no in order to get the simple ratio
⇒ N = 1.5 /0.75= 2
⇒ H = 6.06 /0.75= 8
⇒ S = 0.75/ 0.75= 1
⇒ O = 3.02/ 0.75= 4
Empirical formula = N2 H8 S O4
The empirical formula of the compound is N2 H8 S O4
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