A current is passes through two cell in series. The first cell contain XSO4 while second cell contain Y2SO4. The relative active masses of X & Y are 1:2 what is the ratio ? Mass of X liberated : Mass of Y liberated ?
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According to Faraday's 2nd Law:-
Weight of X deposited(W
1
)∝ Equivalent weight of X[E
1
]
Weight of Y deposited(W
2
)∝ Equivalent weight of y[E
2
]
∴
W
2
W
1
=
E
2
E
1
----------1
∴
W
2
W
1
=
Atomicmass/Valencyofy
Atomicmass/ValencyofX
----------1
For valency of XSO
4
and y
2
SO
4
(i) y
2
SO
4
From Figure-1, we get Valency of SO
4
is 2 and valency of y is 1.
(ii) XSO
4
From Figure-2, both cancel each other.
∴ Valency of X is 2.
From Equation 2,
W
2
W
1
=
1
1
2
2
=
1
1
[∵ Atomic mass ratio of X & y=2:1]
∴
W
2
W
1
=
1
1
.
∴ Mass ratio=1:1.
Explanation:
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