A current of 19296C is passed through an aqueous solution of copper sulphate using copper electrodes . what is the mass in g of copper deposited at the cathode ( molar mass of cu =63.5g mol-1)
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Answer:
The electrode reaction are:
1 mole
Cu
2+
+
2×96500 C
2e
−
→Cu(Cathode)
Cu×Cu
2+
+2e
−
(Anode)
Thus, cathode increases in mass as copper is deposited on it and the anode decreases in mass as copper from it dissolves.
Charge passed through cell =2.68×60×60 coulomb
Copper deposited or dissolved =
2×96500
63.5
×2.68×60×60=3.174 g
Increase in mass of cathode = Decrease in mass of anode =3.174 g.
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