A current strength of 5 through silver nitrate solution in an electrolytic cell form 30 minutes. What is the weight of silver deposited at cathode ? (Given ECE of silver is 0.001118)
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Molar mass of Ag =108 g mol
−1
1 Faraday =96500 C
Q=i×t=1.5 ×5×60=450 Coulombs
Weight of the substance deposited =ZQ
Z=
nF
M
n-factor of AgNO
3
=1
Z=
1×96500
108
Weight of the substance=
96500
108
×450=
9650
54×90
=0.5 g
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