A decrease of free energy accompanying a reaction gives
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For a chemical reaction to be spontaneous, it should have negative value of the Gibbs free energy change ΔG.
ΔG=ΔH−TΔS
Consider following chemical reactions:
A→B , ΔG=+X ......(1)
C→D, ΔG=−Y ...... (2)
If the magnitude of ΔG for second reaction is greater than the magnitude of ΔG for first reaction, ∣Y∣>∣X∣, then if we add the reactions (1) and (2), the ΔG value for the coupled reaction will be negative. Due to this, the coupled reaction would be spontaneous.
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