a) From the following organic compounds given below, choose one compound in each case which relates to the
description [i] to [iii]: [3]
[Ethyne, ethanol, acetic acid, ethene, methane]
i) An unsaturated hydrocarbon used for welding purposes.
ii) An organic compound whose functional group is “– COOH ’’.
iii) A hydrocarbon which on catalytic hydrogenation gives a saturated hydrocarbon.
b) Give a balanced chemical equation for each of the following: [2]
i) Action of alcoholic, hot KOH on bromoethane.
ii) Polymerization reaction of ethene.
c) Write the I.U.P.A.C names of the following compounds - [2x2=4]
i) ii)
d) CH3 – CH3 ? [1]
Question 5 :
a) A compound has the following percentage composition by mass: Carbon 14.4%, Hydrogen1.2% and Chlorine
84.5%. Determine the empirical formula of this compound. Work correct to one decimal place.
The relative molecular mass of this compound is 168, so what is its molecular formula?
(H = 1, C = 12, Cl =35.5) [3+1]
b) i) Why do covalent compounds exist as gases, liquids or soft solids?
ii) Which electrode: anode or cathode is the oxidising electrode? Why? [3]
c) Name the kind of particles present in: [3]
i) Sodium hydroxide solution.
ii) Carbonic acid.
iii) Sugar solution.
Question 6 :
With respect to the electrolysis of lead bromide (PbBr2), answer the following questions:
a) Why is lead bromide maintained in molten state? [1]
b) Why is the electrolytic cell made of silica? [2]
c) Name the ions present in the electrolyte. [2]
d) State what you observe at the cathode and anode. [2]
e) Summarize the electrode reactions. [3]
Question 7 :
a) Write the observations and balance equations for the following reactions –
i) Sodium hydroxide is added drop wise till in excess to a solution of Zinc sulphate. [2]
ii) Ammonium hydroxide is added first in a small quantity and then in excess to a solution of Copper sulphate. [2]
b) Complete and balance the following Chemical reactions: [2x3=6]
i) Na2S2O3 + HCl _____+ ______ + _____+ ______.
ii) FeSO4 + NH4OH ______ + ________.
iii) CuCO3 + dil. HNO3 _______ +_______+ _______.
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