A gas expands from 2 L to 6 L against a constant pressure of
0-atm on absorbing 200 J of heat. The change in internal energy
of the gas will be
(a) -2-6
(b) +26J
(c) 402-6J
(d) -402.63
d
ibh negathat
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Answer: −2.65 J
Explanation:q=200 J;ΔV=6−2=4 lit=0.004 m
3
; P=0.5×101325=50662.5 Pa
ΔH=ΔU+PΔV (enthalpy change)
At const, pressure (for isobar process ) ΔH=q
Hence, ΔU=q−PΔV (1
st
law of theromadynamics )
ΔU=200−50662.5×0.004=200−202.65
ΔU=−2.65 J
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