A gram of salt can be dissolved in 100 ml of water. What factors affect the solubility
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Explanation:
The temp. of solvent and the size of solute
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The solubility of salt(solids) in water is affected by
- The solubility of salt(solids) in water is affected by Temperature
- The solubility of salt(solids) in water is affected by TemperatureCommon ion effect.
- Lattice energy and hydration energy of salt.
Temperature:-
- With an increase in temperature the solubility of solute increases.
- When heating the water, the kinetic energy of water molecules increases. Hence, it can readily break the ionic bond between the molecule of salt.
Common ion effect -
- The common ion effect decreases the solubility of salt.
- If more than one salt is present in a solvent( water) they all ionize in water.
- If the salt contains a common cation or anion, the salt contributes to the concentration of the common ion.
- The reaction shifts to the left, to decrease or to the relieve the stress of excess product (Le chatelier principal)
- As a result solubility of an unsparingly soluble salt is decreased because of the presence of a common ion.
Lattice energy and hydration energy -
- solubility of salt depends upon the lattice energy and hydration energy of salt.
- Lattice energy is equal to the amount of energy required to separate one mole of a solid ionic compound into ions.
- when lattice energy is high the hydration energy is low which implies the high solubility of salt.
- Lattice energy is directly proportional to solubility.
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