A mixture of nitrogen and hydrogen gas has
density 0.505x10-'g cm' at 293 K and 750 mm
Hg pressure. What per cent of the mass is
nitrogen?
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Answer:
We know that PV = n RT= (m/M) RT .
M= dRT /P (Since m/V = density d).
=0.505 x .0821 x 293/ 750 /760 = 12.30gmol-1 .
Let x be the mass fraction of N2 and (1- x) is the mass fraction of H2.
So, x * 28 + (1- x)* 2 = 12.30
26 x = 10.30.
x = 0.39.
% Composition of N2 = 39 % .
% Composition of O2 = 61%.
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