A monatomic ideal gas that is initially at a pressure of 1.50 ✖️ 10 to the power five as a volume of 0.08 m³ compressed adiabatically to a vol of 0.04 m³
What is the final temp?
How much work is done by the gas?
What is the ratio of final temp of the gas to its final temp?
Answers
Explanation:
pressure was released suddenly, so that your 3rd suggestion is correct. With an irreversible expansion against a constant external pressure, the adiabatic equation pVγ=const is inapplicable, so one must use the first law of thermodynamics. Work is done at the expense of the loss of internal energy:
W=−ΔU=nCv(T1−T2)
For ideal monoatomic gas the following is applied:
n=
p1V1
RT1
Cv=
3R
2
so that (1) can be rewritten as such:
W=nCv(T1−T2)=
3p1V1R
2RT1
(T1−T2)=
3p1V1
2
−
3p1V1T2
2T1
At the same time work by gas expansion is
W=p2(V2−V1)=p2V2−p2V1
and from the ideal gas law the reduced product is
p2V2=nRT2
so that (2) can also be rewritten:
W=p2(V2−V1)=nRT2−p2V1
I would leave for OP the task to to equate (1.3) and (2.2) and express the final temperature T2 from there:
3p1V1
2
−
3p1V1T2
2T1
=nRT2−p2V1
Here I bring up the final result:
T2=
3p1V1+2p2V1
5p1V1
T1=
3⋅10 atm⋅10 L+2⋅1 atm⋅10 L
5⋅10 atm⋅10 L
⋅273.15 K=174.7 K
Volume after expansion is also to be found using ideal gas law and (1.1):
V2=
nRT2
p2
=
p1V1RT2
RT1p2
=
p1T2
p2T1
V1=
10 atm⋅174.7 K
1 atm
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