a natural gas has a following composition by volume methane=82%, ethylene=12% N2=6% Calculate the density of gas at 288 k and 101.325kPa and composition in weight%
Answers
Answer:
DENSITY OF A GAS
Recall that the density of a gas is its mass to volume ratio,
ρ=mV
. Therefore, if we can determine the mass of some volume of a gas, we will get its density. The density of an unknown gas can used to determine its molar mass and thereby assist in its identification. The ideal gas law, PV = nRT, provides us with a means of deriving such a mathematical formula to relate the density of a gas to its volume in the proof shown in Example 1.
Example 1
Derivation of a Density Formula from the Ideal Gas Law
Use PV = nRT to derive a formula for the density of gas in g/L
Solution
PV = nRT
Rearrange to get (mol/L):
nv=PRT
Multiply each side of the equation by the molar mass, M
. When moles are multiplied by M in g/mol, g are obtained:(M)(nV)=(PRT)(M) g/L=ρ=PMRT
Check Your Learning
A gas was found to have a density of 0.0847 g/L at 17.0 °C and a pressure of 760 torr. What is its molar mass? What is the gas?
Answer:
ρ=PMRT
0.0847
g/L=760torr×1atm
760torr×M0.0821
Latm/mol K×290KM
= 2.02 g/mol; therefore, the gas must be hydrogen (H2, 2.02 g/mol)
We must specify both the temperature and the pressure of a gas when calculating its density because the number of moles of a gas (and thus the mass of the gas) in a liter changes with temperature or pressure. Gas densities are often reported at STP.
Explanation: