A Q. 1. Write the name, the structure and the magnetic
behaviour of each one of the following
complexes :
(i) [Pt(NH3)2CI(NO2)
(ii) [Co(NH3)4C12] CI
(iii) [Ni(NH3)NO3] CI
(At nos. Co = 27, Ni = 28, Pt = 78)
Car110101
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Answer:
I) [Pt(NH
3
Cl(NO
2
)]
Aminechloridonitrito-n-platinum(II)
Structure is square planar.
Magnetic behavior: Paramagnetic
II) [CO(NH
3
)
4
Cl
2
]Cl
Tetraaminedichloridocobalt chloride(IiI)
Structure is octahedral.
Magnetic behavior: Paramagnetic
III) Ni(CO)
4
Tetra carboxy nickel(0)
Structure is Tetrahedral.
Magnetic behavior: Diamagnetic
Hope it helped you
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