A sample of drinking was found to be contaminated with chloroform. CHCl3 is supposed
to be carcinogen. The level of contamination was 15 ppm (by mass). Express this in %age by
mass. Determine the molality of CHCl3 in water sample
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Answer:
A sample of drinking water was found to be severely contaminated with chloroform (CHCl
3
) supposed to be a carcinogen. The level of contamination was 15 ppm (by mass):
(i) express this in percent by mass
(ii) determine the molality of chloroform in the water sample
Explanation:
15 ppm corresponds to 15 g chloroform in 1000,000 g of solution.
(i) Percent by mass =
Mass of solution
Mass of chloroform
×100
Percent by mass =
1000,000
15
×100=1.5×10
−3
%
(ii) Molality =
Molar mass of chloroform ×(Mass of solution−mass of chloroform)
Mass of chloroform
×1000 (all masses in g)
Molality =
119.5×(1000,000−15)
15
×1000=1.255×10
−4
m.
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