A trivalent metal combines with sulphur to form its sulfide. Give a balanced chemical equation for the above reaction.
Answers
Explanation:
Thallium(I) and thallium(III)–cyclohexylpiperazine dithiocarbamates have been prepared with the same donor environment for the first time and analyzed by electronic, IR, 1H, 13C NMR spectral, CV and single crystal X-ray structural analyses. Solvothermal decomposition of the dithiocarbamates yielded nano Tl4S3 and were characterized. Bond parameters from single crystal X-ray structures have been used in continuous symmetry measure and bond valence sum analysis of the compounds to establish the octahedral geometry and formal oxidation numbers of thallium. [Tl(chpzdtc)]2 (1) shows extensive non covalent interactions and the hemidirected TlS2CSTl core is of distorted square pyramidal geometry with the stereo chemically active lone pair of thallium(I) occupying a vertex of the square pyramid. This is the first report which identifies the 4f7/2 and 4f5/2 electron binding energies of Tl(I) and Tl(III) dithiocarbamates unambiguously and the effect of Tl⋯C interaction on XPS binding energies. [Tl(chpzdtc)3] (2), the trivalent analogue as a contrast is a typical holodirected TlS6 distorted octahedral core with no significant supramolecular interactions. Mean Tl–S bond distances in 1 and 2 are 2.985(7) and 2.6789(19) Å, respectively, which clearly support the higher ease of solvothermal decomposition of 1 to nano Tl4S3 than 2. A strong correlation exists between the bond strengths of Tl–S, the thioureide C–N and the ease of formation of Tl4S3 from the two dithiocarbamates 1 and 2.
Answer:
(a) Hydrogen gas combines with nitrogen to form ammonia.
H
2
(g)+N
2
(g)→NH
3
The balanced equation for this reaction can be written as:
3H
2
(g)+N
2
(g)→2NH
3
(b) Hydrogen sulphide gas burns in air to give water and sulphur dioxide.
H
2
S(g)+O
2
(g)→H
2
O+SO
2
The balanced equation for this reaction can be written as:
2H
2
S(g)+3O
2
(g)→2H
2
O+2SO
2
(c) Barium chloride reacts with aluminium sulphate to give aluminium chloride and a precipitate of barium sulphate.
BaCl
2
+Al
2
(SO
4
)
3
→AlCl
3
+BaSO
4
↓
The balanced equation for this reaction can be written as:
3BaCl
2
+Al
2
(SO
4
)
3
→2AlCl
3
+3BaSO
4
↓
(d) Potassium metal reacts with water to give potassium hydroxide and hydrogen gas.
K+H
2
O→KOH+H
2
The balanced equation for this reaction can be written as:
2K+2H
2
O→2KOH+H
2