A vessel is filled with a gas at a pressure of 76 cm of Hg at a certain temperature. The mass of the gas is increased by 50% by introducing more gas in the vessel at the same temperature. Find out the resultant pressure of the gas.
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Here,
P1 = 76 mmHg
P2 = ?
T1 = T2 = T
Let initial mass of the gas be m1
Increase in mass ∆m/m1 = 0.5
Thus final mass m2 = m1 + 0.5m1 = 1.5m1
Let M be the molecular mass of the gas
Thus, number of moles in the original mass of gas n1 = m1/M
Final number of moles in the gas n2 = m2/M = 1.5n1
Now eqn. of state of the gas in the initial state
P1V= n1 RT ---1.
Eqn. of state in the final state
P2V = n2 RT ---2.
By eqn. 1 and 2
P1 /n1 = P2 /n2
=> P2 = P1 (n2 /n1)
=> P2 = 76 (1.5n1/n1 )
=> P2 = 76×1.5
=> P2 = 114 mm Hg
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