A vessel is filled with an ideal gas at a pressure of 10atm and temp 27degrees. Half of mass of gas is removed
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Pressure will reduce to half on removing the half of the mass of gas.It us because pressure of a gas is directly proportional to mass of the gas.
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Ideal gas equation, P₁V₁/n₁T₁ = P₂V₂/n₂T₂............A
Here, P₁= 10 atm
T₁ = 27° = (27+273) K = 300 K
T₂ = 87° = (87+273) K = 360 K
Now, M₁ = d x V₁ & M₂ = d x V₂
⇒ (M₁/V₁) = (M₂/V₂)
or, (M₁/V₁) = [(M₁/2)/V₂]
or, V₂ = V₁/2
or, V₁ = 2 V₂
thus, equation A can be written as,
(10 X 2 V₂) / 300 = (P₂ X V₂) / 360
or, P₂ = (360 X 20) / 300
or, P₂ = 24
Therefore the final pressure is 24 atm.
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