a. With suitable explanation give the hybridization, geometry and magnetic behavior of
[Ni(CO)4].
b. Give the IUPAC name of the coordination compound:
[ Co Cl2 (en)2] Cl
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a) [Ni(CO)4] has sp3 hybridization. Explain on the basis of valence bond theory that [Ni(CN)4]2– ion with square planar is diamagnetic and the [NiCl4]2– ion with tetrahedral geometry is paramagnetic. ... Therefore, it undergoes sp3 hybridization. Since there are 2 unpaired electrons in this case, it is paramagnetic in nature.
b) Dichlorobis(ethylenediamine)cobalt(III) chloride is a coordination complex with the formula [CoCl2(en)2]Cl (en = ethylenediamine).
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