AB has NaCl type ideal structure. If edge length of
crystal lattice is 282 Å. The radius of A* (approx) is
20.6
41.2 A
32 Å
28.3
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NaCl type lattice is fcc.
By geometry,
Radius of B=
=> r = 1.44×282/4 = 101.5 A°.
Radius of A = 0.414×r = 0.414×101.5 =41.2A°.
Explanation:
A occupies all the octahedral voids and B occupies all the lattice points.
Radius of octahedral void =0.414× Radius of atom at the lattice point.
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