According to Vander Wall's equation, critical coefficient|
RT.
3.
Pvc
is
equal to
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Liquid-Gas Phase Transition and Metastable States
Consider again the Van der Waals equation at temperatures above the critical point: T<TK. ... Any small positive perturbation of the volume dV>0 causes an increase in the gas pressure (since dp>0), which will lead to an explosive expansion of the gas.
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