Chemistry, asked by jyotir51, 4 months ago

Ag
+
 + 
NH
3
 ⇌ 
[Ag(
NH
3
)]
+

k
1
 = 3.5 × 
10
−3
 
[Ag(
NH
3
)]
+
 + 
NH
3
 ⇌ 
[Ag
(
NH
3
)
2
]
+
;
k
2
 = 1.7 × 
10
−3
.  Then the formation constant of 
[Ag
(
NH
3
)
2
]
+
 is
Ag
+
 
+
 
NH
3
 

 
Ag
NH
3
+
;
 
k
1
 
=
 
3
.
5
 
×
 
10
-
3
 
Ag
NH
3
+
 
+
 
NH
3
 

 
Ag
NH
3
2
+
;

k
2
 
=
 
1
.
7
 
×
 
10
-
3
.
 
 
Then
 
the
 
formation
 
constant
 
of
 
Ag
NH
3
2
+
 
is​

Answers

Answered by TheSarcasticSmile
16

Answer:

Ag

+

 + 

NH

3

 ⇌ 

[Ag(

NH

3

)]

+

k

1

 = 3.5 × 

10

−3

 

[Ag(

NH

3

)]

+

 + 

NH

3

 ⇌ 

[Ag

(

NH

3

)

2

]

+

;

k

2

 = 1.7 × 

10

−3

.  Then the formation constant of 

[Ag

(

NH

3

)

2

]

+

 is

Ag

+

 

+

 

NH

3

 

 

Ag

NH

3

+

;

 

k

1

 

=

 

3

.

5

 

×

 

10

-

3

 

Ag

NH

3

+

 

+

 

NH

3

 

 

Ag

NH

3

2

+

;

k

2

 

=

 

1

.

7

 

×

 

10

-

3

.

Then

 

the

 

formation

 

constant

 

of

 

Ag

NH

3

2

+

 

is

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