Aluminum chloride form bridge structure . Why?
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Heating this solid does not produce anhydrous aluminium trichloride, the hexahydrate decomposes to aluminium hydroxide when heated: Al(H2O)6Cl3 → Al(OH)3 + 3 HCl + 3 H2O. Aluminium also forms a lower chloride, aluminium(I) chloride (AlCl), but this is very unstable and only known in the vapour phase.
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