Ammonium heptamolybdate hydrogen peroxide reaction
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H2O2 (MW 34.02)
InChI = 1S/H2O2/c1‐2/h1‐2H
InChIKey = MHAJPDPJQMAIIY‐UHFFFAOYSA‐N
((NH4)6Mo7O24) [12027‐67‐7] H24Mo7N6O24 (MW 1163.88)
((NH4)6Mo7O24·4H2O) [12054‐85‐2] H32Mo7N6O28 (MW 1235.96)
(epoxidation;2 oxidation of secondary alcohols to ketones;2, 3 oxidation of aldehydes to acids;2 chemoselection between epoxidation and alcohol oxidation2, 4)
Physical Data: (NH4)6Mo7O24·4H2O: dec 190 °C; d 2.498 g cm−3.
Solubility: (NH4)6Mo7O24·4H2O: sol H2O (43 g/100 mL); insol alcohol.
Form Supplied in: (NH4)6Mo7O24·4H2O: colorless or slightly greenish or yellowish crystals; widely available.
Handling, Storage, and Precautions: (NH4)6Mo7O24·4H2O: commercially available ammonium heptamolybdate tetrahydrate can be used and stored at rt under air. For H2O2, see Hydrogen Peroxide.
InChI = 1S/H2O2/c1‐2/h1‐2H
InChIKey = MHAJPDPJQMAIIY‐UHFFFAOYSA‐N
((NH4)6Mo7O24) [12027‐67‐7] H24Mo7N6O24 (MW 1163.88)
((NH4)6Mo7O24·4H2O) [12054‐85‐2] H32Mo7N6O28 (MW 1235.96)
(epoxidation;2 oxidation of secondary alcohols to ketones;2, 3 oxidation of aldehydes to acids;2 chemoselection between epoxidation and alcohol oxidation2, 4)
Physical Data: (NH4)6Mo7O24·4H2O: dec 190 °C; d 2.498 g cm−3.
Solubility: (NH4)6Mo7O24·4H2O: sol H2O (43 g/100 mL); insol alcohol.
Form Supplied in: (NH4)6Mo7O24·4H2O: colorless or slightly greenish or yellowish crystals; widely available.
Handling, Storage, and Precautions: (NH4)6Mo7O24·4H2O: commercially available ammonium heptamolybdate tetrahydrate can be used and stored at rt under air. For H2O2, see Hydrogen Peroxide.
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