Ammonium hydrogen sulphide dissociates as: NH_HSs) = NH3(g) + H2SO). Solid NH HS is heated to a temperature TK in a closed vessel containing NH3 at 0.1 atm. If the equilibrium pressure is 0.5 atm. The equilibrium constant K, for the dissociation reaction is:
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Explanation:
total pressure of ammonia + hydrogen sulfide = 1atm
Therefore, pressure of ammonia=pressure of hydrogen sulphide = 1/2
=0.5atm
The values of Kp can be calculated as,
Kp = ( NH3 atm ) ( H2S atm )
Kp =
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