An agitated vessel 6 f t(1.83 m) in diameter contains a six blade
straight blade turbine 2 f t(0.61 m) in diameter, set one impeller
diameter above the vessel floor, and rotating at 80 r/min. It is
proposed to use this vessel for neutralizing a dilute aqueous solution
of N aOH at 70oF with a stoichiometrically equivalent quantity of
concentrated nitric acid (HNO3
). The final depth of liquid in the
vessel is to be 6 f t(1.83 m). Assuming that all the acid is added to
the vessel at one time, how long will it take for the neutralization to
be complete?
Answers
Answer:
The mixing time required for complete neutralization is approximately 1.86 seconds.
Explanation:
We must calculate the mixing time necessary for the acid and NaOH to completely react in order to determine the amount of time needed for the neutralisation to be complete.
The following equation can be used to estimate the mixing time:
where:
tm = mixing time (in seconds)
H = liquid depth in the vessel (in meters)
V = liquid volume in the vessel (in cubic meters)
D = impeller diameter (in meters)
Δρ = density difference between the two fluids (in kg/m³)
Calculating the volume of liquid in the vessel is the first step.
Given that the vessel has a 6 foot diameter and a 6 foot final liquid depth, the capacity can be computed as follows:
= 7.74 m³.
The density difference between the NaOH solution and the HNO₃ solution must then be determined. Given that the concentrated HNO₃ solution has a density of 1500 kg/m³, while the NaOH solution is diluted and has a density of 1000 kg/m³, the density difference can be calculated as follows:
= 500 kg/m³
Using these values as a substitute in the mixing time equation, we obtain:
= 1.86 seconds
As a result, 1.86 seconds of mixing time are needed for full neutralisation.
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