an alkane can show structural isomerism is it has number of a minimum carbon atom
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Positional isomerism is generally exhibited by alkenes, alkynes, alkyl halides, ketones and alcohols etc. So, in an alkane chain, it'd require at least 3 carbons. Example: Propyl bromide (1) and isopropyl bromide (2) are constitutional isomers. They have the same functional group, a bromine atom.
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