An azeotropic solution of two liquids has boiling point lower than that of either of them if it:
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If a mixture of two liquids,shows positive deviation from Raoult's law,then an azeotropic solution of two liquids has boiling point lower than either of the two liquids. ... In this case, vapour in equilibrium with the liquid have compositions away from the azeotropic mixture composition, towards ideal solution.
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