Chemistry, asked by anubhavsinghydv, 2 months ago

An engine working on the Otto cycle, uses hexane (C6H14) as fuel. The engine works on chemically correct air-fuel ratio and the compression ratio is 8. Pressure and temperature at the beginning of compression are 1 bar and 77 ◦C respectively. If the calorific value of the fuel is 43000 kJ/kg and Cv = 0.717 kJ/kg K, find the maximum temperature and pressure of the cycle. Assume the compression follows the law pV 1.3 = c.

Answers

Answered by nitesh000255
0

Explanation:

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Answered by premkrdutta98
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Explanation:

Chapter 3: The First Law of Thermodynamics for Closed Systems

d) The Air-Standard Otto Cycle (Spark-Ignition) Engine

The Air Standard Otto cycle is the ideal cycle for Spark-Ignition (SI) internal combustion engines, first proposed by Nikolaus Otto over 130 years ago, and which is currently used most motor vehicles. The following link by the Kruse Technology Partnership presents a description of the four-stroke Otto cycle operation including a short history of Nikolaus Otto. Once again we have excellent animations produced by Matt Keveney presenting both the four-stroke and the two-stroke spark-ignition internal combustion engine engine operation

The analysis of the Otto cycle is very similar to that of the Diesel cycle which we analysed in the previous section. We will use the ideal "air-standard" assumption in our analysis. Thus the working fluid is a fixed mass of air undergoing the complete cycle which is treated throughout as an ideal gas. All processes are ideal, combustion is replaced by heat addition to the air, and exhaust is replaced by a heat rejection process which restores the air to the initial state.

The most significant difference between the ideal Otto cycle and the ideal Diesel cycle is the method of igniting the fuel-air mixture. Recall that in the ideal Diesel cycle the extremely high compression ratio (around 18:1) allows the air to reach the ignition temperature of the fuel. The fuel is then injected such that the ignition process occurs at a constant pressure. In the ideal Otto cycle the fuel-air mixture is introduced during the induction stroke and compressed to a much lower compression ratio (around 8:1) and is then ignited by a spark. The combustion results in a sudden jump in pressure while the volume remains essentially constant. The continuation of the cycle including the expansion and exhaust processes are essentially identical to that of the ideal Diesel cycle. We find it convenient to develop the analysis approach of the ideal Otto cycle through the following solved problem:

Solved Problem 3.7 - An ideal air-standard Otto cycle engine has a compression ratio of 8. At the beginning of the compression process, the working fluid is at 100 kPa, 27°C (300 K), and 800 kJ/kg heat is supplied during the constant volume heat addition process. Neatly sketch the pressure-volume [P-v] diagram for this cycle, and using the specific heat values for air at a typical average cycle temperaure of 900K determine:

a) the temperature and pressure of the air at the end of each process

b) the net work output/cycle [kj/kg], and

c) the thermal efficiency [ηth] of this engine cycle.

Solution Approach:

The first step is to draw the P-v diagram of the complete cycle, including all the relevant information. We notice that neither volume nor mass have been provided, hence the diagram and solution will be in terms of specific quantities.

We assume that the fuel-air mixture is represented by pure air. The relevant equations of state, internal energy and adiabatic process for air follow:

We recall from the previous section that the nominal specific heat capacity values used for air at 300K are Cv = 0.717 kJ/kg.K,, and k = 1.4. However they are all functions of temperature, and with the extremely high temperature range experienced in internal combustion engines one can obtain significant errors. In this problem we use a typical average cycle temperature of 900K taken from the table of Specific Heat Capacities of Air.

We now go through all four processes in order to determine the temperature and pressure at the end of each process, as well as the work done and heat transferred during each process.

Note that the pressure P4 (as well as P2 above) could also be evaluated from the adiabatic process equation. We do so below as a vailidity check, however we find it more convenient to use the ideal gas equation of state wherever possible. Either method is satisfactory.

We continue with the final process to determine the heat rejected:

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