an ideal solution is that which follows _____ ?
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● An ideal solution is that which vapour pressure follows Raoult's Law.
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An ideal solution is that which follows Raoult's law.
About Raoult's law:
- The vapor pressure of a solvent above a solution, according to Raoult's law, is equal to the vapor pressure of the pure solvent at the same temperature scaled by the mole fraction of the solvent present:
- Where,
- = vapor pressure of the solution
- = mole fraction of the solvent
- = vapor pressure of the pure solvent
Ideal solutions:
- An ideal solution is one in which, regardless of temperature or concentration, each component abides by Raoult's law.
- While the two components are mixed, or when ΔVmixing, there will be no change in volume.
- When the two components are combined, or when there is ΔHmixing there will be no change in enthalpy.
- Example- Benzene+Toluene
Non-Ideal solutions:
- Over the whole concentration range, neither Raoult's law nor Henry's law can be used to describe non-ideal solutions.
- Unsatisfactory results can happen in two ways:
- when the intermolecular interactions between the molecules of the solute and the solvent are weaker than those between molecules that are comparable (of the same kind).
- when the intermolecular forces between molecules are stronger than the forces between molecules that are comparable.
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