An ionic solid a+b crystallises as a fcc structure. If the edge length of cell is 508 pm and radius of anion is 144 pm, the radius of cation is :
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Edge length = a = 508pm
Radius of anion = 144pm (r-)
Radius of cation = ? (r+)
Using formula a = r+/r- , we get:-
508 pm = r+/144 pm
r+ = 508×144 = 73,152 pm
or, r+ = 7.31 cm
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