An ionic solid consists of two elements ‘X’ and ‘Y’. The X- anions form the FCC arrangement and Y+
ions occupy
all the octahedral voids and alternate tetrahedral voids. What is the simplest formula of the compound?
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ANSWER
No of atoms in a CCP unit cell=similar to FCC=4
Therefore no of B atoms present=4
No of A atom=tetrahedral void and octohedral void(4+2)=6
The formula of the compound = A
3
B
2
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