An organic compound containing carbon, hydrogen and oxygen is found to have 40% Carbon,
6.66% Hydrogen and 53.34% oxygen. If molecular mass is 120. Find molecular formula.
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Given :-
- Carbon = 40 %
- Hydrogen = 6.66 %
- Oxygen = 53.34 %
Solution :-
Relative no of atoms
- First we need to divide the % composition of the elements with the atomic mass
Carbon
C = 40 / 12 = 3.33
Hydrogen
H = 6.66 / 1 = 6.66
Oxygen
O = 53.34 / 16 = 3.33
Simple ratio
- Divide all the values obtained above with the least no obtained ( i.e. 3.33 ) in this case
Carbon
C = 3.33 / 3.33 = 1
Hydrogen
H = 6.66 / 3.33 = 2
Oxygen
O = 3.33 / 3.33 = 1
⟹ Empirical formula = CH2O
⟹ Empirical mass = C + 2 (H) + O
⟹ Empirical mass = 12 + 2 (1) + 16
⟹ Empirical mass = 12 + 2 + 16
⟹ Empirical mass = 30g
Molecular mass = n x Empirical mass
⟹ n = Molecular mass / Empirical mass
⟹ n = 120 / 30
⟹ n = 4
Similarly ,
⟹ Molecular formula = n x Empirical formula
⟹ Molecular formula = 4 ( CH2O )
∴ Molecular formula = C 4 H 8 O 4
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