aniline and nitro aniline which one is basic and why
Answers
Answer:
on the other hand, p-nitroaniline has an electron withdrawing group in the para position and due to these EWG the lone pair of NH2 is more stabilized by resonance and availability of the lone pair becomes less than that of aniline. that's why aniline is more basic than p-nitro aniline
Answer:
aniline
Explanation:
look, basicity means the ability of donating electron pair,now aniline has 1 lone pair on the N atom of NH2 group,which is stabilized by resonance in the benzene ring. So,the availability of the lone pair is less.
on the other hand, p-nitroaniline has an electron withdrawing group in the para position and due to these EWG the lone pair of NH2 is more stabilized by resonance and availability of the lone pair becomes less than that of aniline.
that's why aniline is more basic than nitro aniline
Benzoic acid is a carboxylic acid; it has a proton that can be abstracted by a base such as sodium hydroxide or sodium bicarbonate. The 3-nitroaniline is an organic base; there is a lone pair of electrons on the nitrogen atom of the amino group, making 3-nitroaniline a Lewis base (an electron pair donor). p-nitro aniline
Aniline is an organic compound with the formula C6H5NH2. Consisting of a phenyl group attached to an amino group, aniline is the simplest aromatic amine. Its main use is in the manufacture of precursors to polyurethane and other industrial chemicals. Like most volatile amines, it has the odor of rotten fish.