Aniline form m-nitro aniline on nitration why
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During nitration of aniline, m - nitroaniline is also obtained . If direct nitration of aniline is carried, in the presence of these acids, aniline gets protonated to form anilinium ion. ... Hence nitration of aniline gives meta derivative along with ortho and para.
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Aniline,being basic in nature,reacts with acids to form anilinium ion which is meta directing.Hence aniline reacts with nitrating mixture to form considerable amount of meta nitroaniline also,alongwith o-nitroanilne and p-niteoaniline.
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