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a food web...
A food web is the natural interconnection of food chains and a graphical representation of what-eats-what in an ecological community. Another name for food web is consumer-resource system.
a food chain...
A food chain is a linear network of links in a food web starting from producer organisms and ending at apex predator species, detritivores, or decomposer species. A food chain also shows how the organisms are related with each other by the food they eat. Each level of a food chain represents a different trophic level.
detailed difference...
A food chain only follows just one path as animals find food. eg: A hawk eats a snake, which has eaten a frog, which has eaten a grasshopper, which has eaten grass. A food web shows the many different paths plants and animals are connected. eg: A hawk might also eat a mouse, a squirrel, a frog or some other animal.