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Answers
Answer:
Given:
Concentration of OH- is decreased up to 1/4 time
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Need to find:
Change in concentration of Fe3+
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Answer:
》We know, Fe(OH)3 is a solid.
thus [Fe(OH)3] =1
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Stoichiometric coeff of:
Fe =1
OH= 3
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let concentration be Fe initially
be : Fe1
and finally be Fe2
now,
Kc = \dfrac{{concentration \: of \: product}^{coeff} }{{concentration \: of \: product}^{coeff} }Kc=
concentrationofproduct
coeff
concentrationofproduct
coeff
\implies \: Kc1 = {[Fe1]\: ({OH})^{3} }⟹Kc1=[Fe1](OH)
3
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and
Kc2 = {[Fe2] \times ({\dfrac{1}{4}[ OH]})^{3} }Kc2=[Fe2]×(
4
1
[OH])
3
now
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Kc of a reversible reaction can't be different for same reaction at same temperature,
thus
\begin{gathered}Kc1 = Kc2 \\ \implies \: [Fe1] {[OH]}^{3} =[ Fe2] \dfrac{ {[OH]}^{3} }{64}\end{gathered}
Kc1=Kc2
⟹[Fe1][OH]
3
=[Fe2]
64
[OH]
3
\red{\bold{\boxed{\large{ \implies \: [Fe2] = 64[Fe1]}}}}
⟹[Fe2]=64[Fe1]
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Thus The new concentration of Fe will be 64times of initial concentration.