Chemistry, asked by Meenabouddh3, 8 months ago

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Answered by adn9262ansari
1

Explanation:

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Answered by Anonymous
2

Given Question:

Calculate the wavelength corresponding to transition from n1 =1 to n2 =4 in Lyman series.

To Find :

Wavelength

Formula used :

 \frac{1}{λ} = R {z}^{2} ( \frac{1}{ {n1}^{2}  } -  \frac{1}{ {n2}^{2}  })

Here, λ is the wavelength, R is Rydberg's constant and z =1 [H] is Atomic number.

Solution :

The Lyman series is the first line of transition and is hydrogen spectral series.It lies both in emission as well as absorption spectrum.

 \frac{1}{λ} = R {z}^{2} ( \frac{1}{ {n1}^{2}  } -  \frac{1}{ {n2}^{2}  })

According to the question, we need to find the wavelength so ;

λ =  \frac{1}{R( \frac{1}{ {n1}^{2} }  - {\frac{1}{ {n2}^{2} } }) }

As we know,

R (constant)  = 1.1 \times  {10}^{ - 7} {m} ^{-1}

And,

 \frac{1}{R} = 912 \: Å \:

Hence,on solving further

λ =  \frac{1}{R( \frac{1}{ {n1}^{2} }  - {\frac{1}{ {n2}^{2} } }) } \:  \\  \\ λ =   \frac{1}{ R \:(  \frac{1}{ {1}^{2}  }   -  \frac{1}{ {4}^{2} } )} \\  \\ λ =  \frac{1}{R \times  \frac{15}{16}} \\  \\  λ = 912 \times  \frac{16}{15} Å \:

λ = 972.8 \: Å \:

Therefore,the wavelength of transition in the Lyman series is 972.8 Å.

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