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Explanation:
The number of moles of water in 100 g =18100=5.555
Let n be the number of moles of solute.
The relative lowering in the vapour pressure is equal to the mole fraction of solute
P0P0−P=X
760760−732=n+5.555n
0.0368=n+5.555n
27.144=n+5.555
n=26.145.555=0.212
The molality of the solution is the number of moles of solute in 1 kg of water
100 g of water corresponds to 0.1 kg
m=0.10.212=2.12
The elevation in the boiling point is
ΔTb=kbm=0.52×2.12=1.1oC
The boiling point of the solution is
Tb=100+1.1=101.1oC≃101oC
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