anti markovnikov rule definition
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When a reaction takes place in the presence of peroxide and a catalyst.. Then the negative part(anionic) of catalyst will go and bond with carbon having higher number of hydrogen atoms and postive part(cationic) will attach to the carbon atom having less number of hydrogen atoms.
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Anti-Markovnikov rule describes the regiochemistry where the substituent is bonded to a less substituted carbon, rather than the more substitued carbon. ... This is because substituted carbocation allow more hyperconjugation and indution to happen, making the carbocation more stable.
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