Are the lines in rotational Raman spectra are equally spaced?
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==>In consequence, the spacing between lines is not constant, as in the rigid rotor approximation, but decreases with increasing rotational quantum number.
Explanation:
==>► Raman spectroscopy is less restrictive than pure rotational spectroscopy: Linear symmetric molecules do have rotational Raman spectra. ) do not have pure rotational spectra (do not possess permanent dipole moments). still do not have rotational Raman spectra as they do not have an anisotropic polarizability.
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In consequence, the spacing between lines is not constant, as in the rigid rotor approximation, but decreases with increasing rotational quantum number.
Explanation:
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