arrange homolytic bond energies of c-h bond designated by 1 2 3 4
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C
z>y>x
Bond dissociation energy in hamolytic cleavage is directly prpoprtional to the bond strength as z→sp2 hybridised → more strong than y and x
y→ having partial sp2 character because of hyperconjugation.
x→ No hyperconjugation, purely sp3→ weakest bond.
Bond dissociation energy order is
z>y>x
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